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In an analytical chemistry laboratory, a student calibrates a spectrophotometer absorbance reading using the relationship , where denotes the dimensionless absorbance. Determine all valid experimental absorbance values , rounded to three significant figures.
Answer and steps
Final answer
or
Steps
To solve an absolute value equation of the form where , recall that the expression inside the absolute value can equal either or :
Here, let and . Setting up the two linear equations:
Case 1: Positive branch
Add to both sides:
Divide both sides by :
Case 2: Negative branch
Add to both sides:
Divide both sides by :
Verification and Significant Figures
- Both values and are positive and physically reasonable for spectrophotometer absorbance readings.
- Writing each to three significant figures gives and .
Typical errors
01 The student ignores the absolute value bars and solves only the positive case, missing the second valid solution.
Sample Student Work
Reviewed by ACEpath TeacherStep-by-Step Review
Walk Through It with Your Teacher- Step 1
0.850 A - 0.510 = 0.068
Correct0.850 A - 0.510 = 0.068 0.850 A - 0.510 = -0.068
An absolute value equation of the form (where ) requires two separate cases: and . Removing the bars without setting up the negative case discards half of the solution set.
- Step 2
0.850 A = 0.578 A = 0.578 / 0.850
- Step 3
A = 0.680
CorrectA = 0.520 A = 0.680
This numerical value is correct for the positive branch, but the final answer remains incomplete because the second valid value from the negative branch was never evaluated.
WHAT YOU DID WELL
Compliments from Your TeacherYou correctly isolated the variable term and carried out the arithmetic for the positive branch.
You correctly reported your value with three significant figures.
THE ERROR
Where Your ACEpath Teacher Spotted the MistakeYou treated the absolute value expression as standard parentheses and solved only the positive case.
WHY IT HAPPENED
ACEpath Teacher's DiagnosisThe definition of absolute value as distance on a number line was overlooked: means lies a distance of away from zero in either direction, requiring both and .
REASONING PATH
Your ACEpath teacher’s suggested approach- Split Before Solving
For any equation with , immediately write down two distinct equations: and .
Whenever you remove absolute value bars, write an explicit 'or' statement with both and before performing any algebra.
- Check Solution Count
A linear absolute value equation with yields two distinct solutions.
Count your final answers; if you only have one value for a non-zero distance, pause and find the missing branch.
CORRECTED PATH
ACEpath Teacher's DemonstrationSet up the two branches from : Branch 1 is , and Branch 2 is .
Solve Branch 1: .
Solve Branch 2: .
or
02 The student negates only the variable term inside the absolute value rather than the entire expression or the right-hand side, leading to an incorrect negative absorbance value.
Sample Student Work
Reviewed by ACEpath TeacherStep-by-Step Review
Walk Through It with Your Teacher- Step 1
0.850 A - 0.510 = 0.068 -0.850 A - 0.510 = 0.068
Correct0.850 A - 0.510 = 0.068 -(0.850 A - 0.510) = 0.068 0.850 A - 0.510 = -0.068
To branch an absolute value equation , you must negate the entire enclosed expression , or equivalently negate the constant side . Negating only the leading term while leaving unchanged is mathematically invalid.
- Step 2
0.850 A = 0.578 A = 0.680
- Step 3
-0.850 A = 0.578 A = = -0.680
Correct0.850 A - 0.510 = -0.068 0.850 A = 0.442 A = 0.520
Your algebraic isolation here was executed consistently with the equation you wrote, but it inherits the setup error from Step 1.
- Step 4
A = 0.680 A = -0.680
CorrectA = 0.520 A = 0.680
Because the second branch was set up incorrectly, your final combined set of values includes instead of .
WHAT YOU DID WELL
Compliments from Your TeacherYou correctly recognized that an absolute value equation splits into two linear branches.
You accurately solved the linear equation for the positive branch to find .
THE ERROR
Where Your ACEpath Teacher Spotted the MistakeYou applied the negative sign to only the first term instead of distributing it across the entire binomial or applying it to the right-hand constant .
WHY IT HAPPENED
ACEpath Teacher's DiagnosisConfusing the negation of an entire algebraic expression with changing the sign of just the leading variable term. In , the opposite branch is , which equals , or more simply .
REASONING PATH
Your ACEpath teacher’s suggested approach- Rule for Branching $|X| = c$
For any real expression and constant , splits into or .
Keep the entire expression inside the absolute value unchanged on the left side, and place the sign on the single number on the right side.
- Physical Reality Check
Spectrophotometer absorbance is typically non-negative under standard calibration conditions.
When you obtain a negative absorbance like , pause and verify whether you correctly handled the negative branch.
CORRECTED PATH
ACEpath Teacher's DemonstrationRewrite Case 2 by placing the negative sign on the constant: .
Add to both sides: .
Divide by : .
or
03 When solving the negative case, the student adds 0.510 incorrectly by computing 0.068 - 0.510 instead of -0.068 + 0.510, arriving at an erroneous absorbance value.
Sample Student Work
Reviewed by ACEpath TeacherStep-by-Step Review
Walk Through It with Your Teacher- Step 1
- Step 2
- Step 3Correct
When adding to both sides of , the right-hand side is . You dropped the negative sign on and subtracted instead.
- Step 4Correct
Your division arithmetic was executed consistently, but the value carried the incorrect negative sign from the previous line.
- Step 5Correct
The final pair of solutions contains the propagated sign error from the negative branch.
WHAT YOU DID WELL
Compliments from Your TeacherYou split the absolute value equation into the correct positive and negative cases.
You solved the positive branch completely and rounded properly to three significant figures.
You carried out the division step with correct arithmetic.
THE ERROR
Where Your ACEpath Teacher Spotted the MistakeWhen isolating in the second branch, you wrote rather than keeping and adding .
WHY IT HAPPENED
ACEpath Teacher's DiagnosisLosing track of existing negative signs on the right-hand side when applying inverse operations to the constant term on the left.
REASONING PATH
Your ACEpath teacher’s suggested approach- Keep Existing Signs Explicit
When solving , adding to both sides yields , which equals .
Always write out explicitly on both sides before combining terms.
- Physical Reality Check
In spectrophotometry, standard absorbance values are non-negative for transmitting samples.
Pause and re-check algebraic signs whenever an intermediate or final physical quantity yields an unexpected negative value.
CORRECTED PATH
ACEpath Teacher's DemonstrationAdd to both sides: .
Divide both sides by : .
or
Lock it in
What two equations must you write when solving , where ?
or . Absolute value represents distance from zero, which can lie in either the positive or negative direction.
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